Mr Richard Nwora Madiebo was also appointed as the Chairman, Anambra State Internal Revenue Service (AIRS).
This latest development was revealed in a statement issued by Soludo in Awka.
The appointments bring to six political appointees the Governor has made since March 17 he took over.
Ezeajughi, a former Mayor of London Borough of Brent hails from Awgbu in Orumba Local Government Area.
Soludo had on Thursday few hours after his inauguration announced his first appointments with Prof Solo Chukwulobelu as the Secretary to the State Government, Dr Chukwudi Okoli as the state Accountant General and Mr Chinedu Nwoye as the Deputy Chief of Staff.